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<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" dtd-version="3.0">
  <front>
    <journal-meta>
<journal-id journal-id-type="publisher">DWES</journal-id>
<journal-title-group>
<journal-title>Drinking Water Engineering and Science</journal-title>
<abbrev-journal-title abbrev-type="publisher">DWES</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Drink. Water Eng. Sci.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1996-9465</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>

    <article-meta>
      <article-id pub-id-type="doi">10.5194/dwes-10-13-2017</article-id><title-group><article-title>Riverbank filtration for the treatment of highly turbid Colombian rivers</article-title>
      </title-group><?xmltex \runningtitle{RBF for highly turbid rivers}?><?xmltex \runningauthor{J. P. Guti\'{e}rrez et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1 aff2">
          <name><surname>Gutiérrez</surname><given-names>Juan Pablo</given-names></name>
          <email>j.p.gutierrezmarin@tudelft.nl</email><email>juan.p.gutierrez@correounivalle.edu.co</email>
        <ext-link>https://orcid.org/0000-0003-2692-8491</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>van Halem</surname><given-names>Doris</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Rietveld</surname><given-names>Luuk</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>Civil Engineering Department, Delft University of Technology, Delft,
2628 CN, the Netherlands</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Cinara Institute, Faculty of Engineering, 760032 Cali, Colombia</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Juan Pablo Gutiérrez (j.p.gutierrezmarin@tudelft.nl, juan.p.gutierrez@correounivalle.edu.co)</corresp></author-notes><pub-date><day>11</day><month>May</month><year>2017</year></pub-date>
      
      <volume>10</volume>
      <issue>1</issue>
      <fpage>13</fpage><lpage>26</lpage>
      <history>
        <date date-type="received"><day>21</day><month>February</month><year>2017</year></date>
           <date date-type="rev-request"><day>23</day><month>February</month><year>2017</year></date>
           <date date-type="accepted"><day>20</day><month>April</month><year>2017</year></date>
      </history>
      <permissions>
<license license-type="open-access">
<license-p>This work is licensed under a Creative Commons Attribution 3.0 Unported License. To view a copy of this license, visit <ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/3.0/">http://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions><self-uri xlink:href="https://dwes.copernicus.org/articles/10/13/2017/dwes-10-13-2017.html">This article is available from https://dwes.copernicus.org/articles/10/13/2017/dwes-10-13-2017.html</self-uri>
<self-uri xlink:href="https://dwes.copernicus.org/articles/10/13/2017/dwes-10-13-2017.pdf">The full text article is available as a PDF file from https://dwes.copernicus.org/articles/10/13/2017/dwes-10-13-2017.pdf</self-uri>


      <abstract>
    <p>The poor quality of many Colombian surface waters forces us
to
seek alternative, sustainable treatment solutions with the ability to
manage peak pollution events and to guarantee the uninterrupted provision of
safe drinking water to the population. This review assesses the potential of
using riverbank filtration (RBF) for the highly turbid and contaminated
waters in Colombia, emphasizing water quality improvement and the influence
of clogging by suspended solids. The suspended sediments may be favorable for
the improvement of the water quality, but they may also reduce the production yield
capacity. The cake layer must be balanced by scouring in order for an RBF
system to be sustainable. The infiltration rate must remain high enough
throughout the river–aquifer interface to provide the water quantity
needed, and the residence time of the contaminants must be sufficient to ensure
adequate water quality. In general, RBF seems to be a technology
appropriate for use in highly turbid and contaminated surface rivers in
Colombia, where improvements are expected due to the removal of turbidity, pathogens
and to a lesser extent inorganics, organic matter and micro-pollutants. RBF has the potential to mitigate shock loads, thus leading to the
prevention of shutdowns of surface water treatment plants. In addition, RBF,
as an alternative pretreatment step, may provide an important reduction in
chemical consumption, considerably simplifying the operation of the
existing treatment processes. However, clogging and self-cleansing issues
must be studied deeper in the context of these highly turbid waters to
evaluate the potential loss of abstraction capacity yield as well as the
development of different redox zones for efficient contaminant removal.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p>Riverbank filtration (RBF) is a water abstraction technology that consists of
production wells that extract water some distance away from a surface water
body (Fig. 1). As the production wells pump water from the aquifer, surface
water flows underground to recharge it, while the subsurface sediments
function as a natural filter that removes several contaminants, producing
higher quality water than the raw source water (Schubert,
2003; Sontheimer, 1980; Tyagi et al., 2013). In addition, the naturally
present groundwater contributes to the higher water quality extracted from
RBF systems, e.g., through attenuation (Kuehn and Mueller, 2000) and
the change in redox conditions (Bourg, 1992; Hiscock
and Grischek, 2002).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><caption><p>A general representation of a horizontal RBF system.</p></caption>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://dwes.copernicus.org/articles/10/13/2017/dwes-10-13-2017-f01.png"/>

      </fig>

      <p>The well configuration in RBF systems can be either vertical or horizontal, offering different benefits. Vertical wells are commonly used for
longer residence or travel times to ensure higher removal efficiencies of
more mobile contaminants. Horizontal wells are usually applied to obtain
higher water flows, but they may be unfavorable for the quality of the
water abstracted due to shorter residence times (Hunt et
al., 2003; Ray, 2002b).</p>
      <p>Many variables influence the performance of RBF systems, including riverbed
media composition and the hydraulic connectivity of the aquifer
(Hubbs et al., 2007; Hunt et al., 2003;
Schubert, 2002). In Europe and the United States, RBF has been widely used
because of the favorable hydraulic conditions
(Brunke,
1999; Goldschneider et al., 2007; Hubbs et al., 2007; Stuyfzand et al.,
2006; Veličković, 2005). In addition, RBF has a demonstrated ability
to be an effective water treatment technology for contaminated surface
waters (Singh et al.,
2010; Thakur and Ojha, 2010).</p>
      <p>A key water quality parameter determining the performance of RBF systems is
the concentration of total suspended solids (TSS) contained in the surface
water; this is because long-term changes in the composition and concentration of
suspended solids can have potential cumulative effects on the clogging of
riverbanks and alluvial aquifers. In addition, suspended solids generally
act as the primary transport mechanism for emerging organisms and pollutants
(Bourg et al.,
1989; Miretzky et al., 2005; Stone and Droppo, 1994; Zhu et al., 2005).
Turbidity is one of the parameters used to indirectly describe the
concentration of suspended solids (EPA, 1999), which can be conveniently
measured due to the strong relationship between the two parameters
(Susfalk et al., 2008;
Wu et al., 2014) and the relatively long analysis time of TSS compared to
turbidity analysis (Susfalk et al., 2008).</p>
      <p>RBF has the additional advantage of removing or attenuating certain heavy
metals (Bourg and Bertin, 1993; Stuyfzand,
1998), pathogens
(Dillon
et al., 2002; Schijven et al., 2003; Schmidt et al., 2003; Sprenger et al.,
2014; Weiss et al., 2005) and nutrients
(Krause et al., 2013;
Ray, 2002b; Schmidt et al., 2003; Wu et al., 2007). In addition, RBF has
demonstrated an ability to decrease mutagenic compounds, including naproxen,
gemfibrozil and ibuprofen (Hoppe-Jones et
al., 2010; Schubert, 2003), and to remove organic and inorganic
micro-pollutants, such as sulfamethoxazole and propranolol
(Bertelkamp
et al., 2014; Hamann et al., 2016; Schmidt et al., 2003). However, it has
also been found that specific micro-pollutants such as carbamazepine and
EDTA remain mobile, showing persistent behavior even after 3.6 years of
travel time (Hamann et al., 2016).
The persistence is mainly driven by the very low reactive and sorptive
characteristics of these compounds
(Scheytt et al., 2006). RBF has also
shown the capacity to mitigate shock loads
(Mälzer et al., 2003; Schmidt et al., 2003),
resulting in a stable abstracted water quality.</p>
      <p>Although RBF has been shown to be highly effective in the removal of many
contaminants, it must mainly be considered as a pretreatment method that
needs to be combined with a certain posttreatment
(Cady
et al., 2013; Dash et al., 2008; Kuehn and Mueller, 2000; Singh et al.,
2010). A balance between the water quality and the production capacity must
be considered; greater removal efficiencies are achieved by increasing
travel distances, but this can decrease the rate of productivity.</p>
      <p>Surface water bodies are the main sources of drinking water
for the Colombian communities and make up approximately 80 % of the systems
(Ministerio de Desarrollo de Colombia, 1998). However, in the
last decades, turbidity and contamination events in surface waters have
become a serious concern in Colombia in the context of guaranteeing safe drinking water
(Gutiérrez et al., 2016; Universidad del Valle and
UNESCO-IHE, 2008). Fast urbanization, the lack of integration between water
management and spatial planning and inappropriate land use are identified
as the main causes for the progressive deterioration of the surface water
(IDEAM, 2015; van der Kerk, 2011; Universidad
del Valle and UNESCO-IHE, 2008). Figure 2 illustrates the variation in monthly turbidity percentiles
in the Cauca River (Cali, Colombia) for the years
2008–2013 (EMCALI; J. C. Escobar, personal communication,  2015). High turbidity
events in the Cauca River lead to intake shutdowns in the main water
treatment plant (Puerto Mallarino WTP) in the city of Cali, where
turbidity peaks of up to 10 000 NTU (Fig. 2) have been reported. The decrease in the
dissolved oxygen
concentrations in the Cauca River is used as an indicator of high pollution
peaks. It typically drops after heavy rainfalls with the increase in organic
matter concentrations (CVC and Universidad del Valle, 2004).</p>
      <p>The Pacific basins of Colombia have sediment yields between 1150 and
1714 t km<inline-formula><mml:math id="M1" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> yr<inline-formula><mml:math id="M2" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (Restrepo and Kjerfve, 2004), while
the Magdalena River in the Magdalena–Cauca basin, which corresponds to the
most populated zone in the country, has the highest sediment yield (560 t km<inline-formula><mml:math id="M3" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> yr<inline-formula><mml:math id="M4" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) of the large rivers in the Caribbean and on the Atlantic coast of
South America; this is similar to the yields found in the larger basins of
southern Asian rivers (Restrepo et al., 2009). In addition,
significant loads of heavy metals (up to 122 kg d<inline-formula><mml:math id="M5" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> Hg; 2600 kg d<inline-formula><mml:math id="M6" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> Pb;
3300 k d<inline-formula><mml:math id="M7" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> Cd; 490 kg d<inline-formula><mml:math id="M8" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> Cr) and nutrients (up to 1 138 000 kg d<inline-formula><mml:math id="M9" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> N and
769 000 kg d<inline-formula><mml:math id="M10" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> P) have been found in the sediments of the Magdalena River (IDEAM,
2011).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><caption><p>Turbidity percentile values in the Cauca River in Colombia during the years
2008–2013.</p></caption>
        <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://dwes.copernicus.org/articles/10/13/2017/dwes-10-13-2017-f02.png"/>

      </fig>

      <p>Considering the poor quality of many Colombian surface waters, there
is a need to seek alternative, sustainable treatment solutions with the
ability to manage peak pollution events and to guarantee the uninterrupted
provision of safe drinking water to the population. RBF has been shown to be
effective in the removal of many river water pollutants and can therefore
also be of interest for drinking water companies and environmental and
public health authorities in Colombia
(Hülshoff et al., 2009; Schijven
et al., 2003; Schmidt et al., 2003; Schubert, 2003).</p>
      <p>The few reported experiences with RBF in highly turbid and contaminated
surface waters led to this review to assess the potential of
using RBF for the highly turbid waters in Colombia by emphasizing water
quality improvement and the influence of clogging by suspended solids.</p>
</sec>
<sec id="Ch1.S2">
  <title>Water quality improvement</title>
<sec id="Ch1.S2.SS1">
  <title>Mechanisms of water quality improvement in RBF systems</title>
      <p>RBF removes contaminants through filtration, sorption of pollutants to soil
particles, microbial degradation, chemical precipitation, ion exchange and
oxidation and reduction (Schmidt et al., 2003; Schubert,
2003). In the first centimeters of the riverbed, a fine sediment layer is
formed, also known as a cake layer. The cake layer is called a schmutzdecke if a
highly active biological layer is involved
(Hiscock and Grischek, 2002; Unger and Collins,
2006). A certain degree of clogging in the riverbed is preferred since it
can be favorable for water quality improvement (Ray and Prommer,
2006) due to the augmentation of traveling times, particulate removal and
the richness of the processes occurring in the schmutzdecke
(Hiscock and Grischek, 2002; Schmidt et
al., 2003; Unger and Collins, 2006). Jüttner (1995) determined that the schmutzdecke and the upper layers were
responsible for most of the elimination of volatile organic carbon, and
Dizer et al. (2004) concluded that this
layer is extremely efficient in eliminating viruses.
Maeng et al. (2008) found
that 50 % of the total dissolved organic matter removal in a simulated
RBF system occurred in the first few centimeters of the infiltration surface due
to the biological activity in the developed biomass. In the schmutzdecke, the removal of organic matter, pathogens and chemicals occurs through
predation, scavenging and metabolic breakdown mechanisms
(Haig et al., 2011). A cake layer, mainly
composed of organic and/or clay constituents, may also enhance the sorption
of pollutants onto its surface (Li
et al., 2003).</p>
      <p>The interface between the surface water and the groundwater, corresponding to the hyporheic
zone (Fig. 1), plays the most important role in the degradation of
contaminants
(Doussan
et al., 1997; Grischek and Ray, 2009; Maeng et al., 2008; Smith et al.,
2009; Stuyfzand, 2011). The hyporheic zone is characterized by redox
gradients, the dynamic exchange of oxygen and the presence of organic carbon and
microorganisms
(Doussan et
al., 1997; Febria et al., 2012; Findlay and Sobczak, 2000) that enhance
electron transfer, ion exchange and degradation and sorption processes,
therefore improving the removal of pollutants
(Hiscock and Grischek,
2002; Smith, 2005; Tufenkji et al., 2002). Commonly, microbial activity is
high in the early stages of infiltration, depleting the
oxygen in the hyporheic zone and producing anoxic or anaerobic conditions
(Doussan et al.,
1997; Krause et al., 2013).</p>
      <p>The flow path between the river and the abstraction well is characterized by
lower biological activity and sorption capacity as well as longer retention
times and increased mixing (Hiscock
and Grischek, 2002; Stuyfzand, 2011). This flow path is therefore of great
importance for the removal of poorly degradable pollutants, which require
greater distances to be removed or inactivated. In both the hyporheic zone
and the flow path, deep bed filtration mechanisms are important.</p>
      <p>During deep bed filtration, the particles in suspension to be removed are
considerably smaller than the average size of the aquifer pores
(Brunke, 1999;
Sutherland, 2008; Zamani and Maini, 2009). Therefore, particle separation
mainly occurs due to selective straining within the porous media through
sedimentation, interception, inertial forces or Brownian motion
(Sutherland, 2008). Pathogens are mainly removed from the water
through straining, inactivation and attachment to the soil grains
(Schijven et al., 2003).</p>
      <p>The transformation of nutrients in the subsoil is a function of the
exchange rates between the river and hyporheic zone, residence times, dissolved oxygen and
biotic processes
(Krause et
al., 2013; Smith, 2005). The hyporheic zone may have anoxic or anaerobic
conditions due to high levels of microbial activity
(Doussan et al.,
1997; Krause et al., 2013). If the consumption of oxygen exceeds the
hydrological oxygen exchange rate, anoxic conditions lead to an oxic–anoxic
interface. The reduced and oxidized forms of the nutrients may coexist
under such conditions (Duff and Triska, 2000).</p>
      <p>The removal of heavy metals from source water during subsurface passage
mainly occurs through sorption, precipitation and ion exchange processes, which
depend on the content of the inorganic and organic compounds in the aquifer and
the contact time (Bourg et al., 1989; Hülshoff
et al., 2009). Under aerobic conditions, heavy metal removal is mainly
attributed to ion exchange processes at negatively loaded surfaces
(Schmidt et al., 2003). The presence of negatively charged
surfaces (e.g., clayey and/or organic sediments) and amorphous ferric and
aluminum oxides provide exchange sites for binding trace heavy metals
(Foster and Charlesworth, 1996; Salomons and
Förstner, 1984). As contact time is a critical parameter affecting the
fate of most heavy metals, the removal of such compounds through ion exchange
processes mainly occurs in the hyporheic zone and the flow path between the
river and the abstraction well
(Hülshoff et al., 2009; Stuyfzand,
2011). In anoxic aquifers, heavy metals are mainly removed through sorption
processes (Schmidt and Brauch, 2008). If the conditions are
such that sulfide is formed, the immobilization of heavy metals may occur
through sulfide precipitation (Bourg et al., 1989;
Salomons and Förstner, 1984).</p>
      <p>Micro-pollutants occur in most surface waters that run through heavily
polluted regions or large industrial and agricultural areas. The fate of
such substances in RBF systems is mainly determined by sorption mechanisms
and biological transformations (Schmidt et al., 2003).
During absorption, hydrophobic interactions occur between the aliphatic and
aromatic groups of micro-pollutants and the membrane cells of the
microorganisms. During adsorption, the negatively charged surfaces of the
microorganisms and the soil lead to electrostatic interactions of the
positively charged micro-pollutants (Luo et al.,
2014).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><caption><p>Turbidity removal at bank filtration sites with highly turbid raw
water sources.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="6">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:colspec colnum="5" colname="col5" align="left"/>
     <oasis:colspec colnum="6" colname="col6" align="left"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Bank filtration</oasis:entry>  
         <oasis:entry colname="col2">Pant Dweep Island at</oasis:entry>  
         <oasis:entry colname="col3">Indiana American</oasis:entry>  
         <oasis:entry colname="col4">Indiana American</oasis:entry>  
         <oasis:entry colname="col5">Missouri American</oasis:entry>  
         <oasis:entry colname="col6">Louisville,</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">site</oasis:entry>  
         <oasis:entry colname="col2">Haridwar, India</oasis:entry>  
         <oasis:entry colname="col3">Water at</oasis:entry>  
         <oasis:entry colname="col4">Water at Terre</oasis:entry>  
         <oasis:entry colname="col5">Water at Parkville,</oasis:entry>  
         <oasis:entry colname="col6">Kentucky,</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">(Dash et al., 2010)</oasis:entry>  
         <oasis:entry colname="col3">Jeffersonville, USA</oasis:entry>  
         <oasis:entry colname="col4">Haute, USA</oasis:entry>  
         <oasis:entry colname="col5">USA</oasis:entry>  
         <oasis:entry colname="col6">USA</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">(Thakur and Ojha, 2010)</oasis:entry>  
         <oasis:entry colname="col3">(Weiss et al., 2005)</oasis:entry>  
         <oasis:entry colname="col4">(Weiss et al., 2005)</oasis:entry>  
         <oasis:entry colname="col5">(Weiss et al., 2005)</oasis:entry>  
         <oasis:entry colname="col6">(Wang, 2003)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">Distance from</oasis:entry>  
         <oasis:entry colname="col2">320 m (V)</oasis:entry>  
         <oasis:entry colname="col3">177 m (V)</oasis:entry>  
         <oasis:entry colname="col4">24 m (H)</oasis:entry>  
         <oasis:entry colname="col5">37 m (V)</oasis:entry>  
         <oasis:entry colname="col6">23 (V)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">source water</oasis:entry>  
         <oasis:entry colname="col2">108 m (V)</oasis:entry>  
         <oasis:entry colname="col3">30 m (V)</oasis:entry>  
         <oasis:entry colname="col4">122 m (V)</oasis:entry>  
         <oasis:entry colname="col5">37 m (V)</oasis:entry>  
         <oasis:entry colname="col6">24 (H)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">V: vertical</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6"/>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">H: horizontal</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Travel time (d)</oasis:entry>  
         <oasis:entry colname="col2">420–510</oasis:entry>  
         <oasis:entry colname="col3">13–19</oasis:entry>  
         <oasis:entry colname="col4">NA</oasis:entry>  
         <oasis:entry colname="col5">NA</oasis:entry>  
         <oasis:entry colname="col6">2–5</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">32.5</oasis:entry>  
         <oasis:entry colname="col3">3–5</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Source water</oasis:entry>  
         <oasis:entry colname="col2">200</oasis:entry>  
         <oasis:entry colname="col3">661</oasis:entry>  
         <oasis:entry colname="col4">1761</oasis:entry>  
         <oasis:entry colname="col5">1521</oasis:entry>  
         <oasis:entry colname="col6">599</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">(maximum</oasis:entry>  
         <oasis:entry colname="col2">2500</oasis:entry>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6"/>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">turbidity; NTU)</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Bank filtration</oasis:entry>  
         <oasis:entry colname="col2">0.6</oasis:entry>  
         <oasis:entry colname="col3">1.1</oasis:entry>  
         <oasis:entry colname="col4">0.27</oasis:entry>  
         <oasis:entry colname="col5">3.8</oasis:entry>  
         <oasis:entry colname="col6"><inline-formula><mml:math id="M11" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.8</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">system (maximum</oasis:entry>  
         <oasis:entry colname="col2">Not available</oasis:entry>  
         <oasis:entry colname="col3">1.5</oasis:entry>  
         <oasis:entry colname="col4">0.41</oasis:entry>  
         <oasis:entry colname="col5">2.7</oasis:entry>  
         <oasis:entry colname="col6">0.69</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">turbidity; NTU)</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Turbidity</oasis:entry>  
         <oasis:entry colname="col2">99.7</oasis:entry>  
         <oasis:entry colname="col3">99.83</oasis:entry>  
         <oasis:entry colname="col4">99.98</oasis:entry>  
         <oasis:entry colname="col5">99.75</oasis:entry>  
         <oasis:entry colname="col6"><inline-formula><mml:math id="M12" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>99.8</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">removal (%)</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M13" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>99.9</oasis:entry>  
         <oasis:entry colname="col3">99.77</oasis:entry>  
         <oasis:entry colname="col4">99.98</oasis:entry>  
         <oasis:entry colname="col5">99.82</oasis:entry>  
         <oasis:entry colname="col6">99.88</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Aquifer material</oasis:entry>  
         <oasis:entry colname="col2">Sand, clayey and</oasis:entry>  
         <oasis:entry colname="col3">Clay, fine and</oasis:entry>  
         <oasis:entry colname="col4">Medium and fine</oasis:entry>  
         <oasis:entry colname="col5">Fine to coarse</oasis:entry>  
         <oasis:entry colname="col6">Sand and</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">silty sands</oasis:entry>  
         <oasis:entry colname="col3">medium sands,</oasis:entry>  
         <oasis:entry colname="col4">sands underlain</oasis:entry>  
         <oasis:entry colname="col5">sand, gravel</oasis:entry>  
         <oasis:entry colname="col6">gravel with</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3">coarse gravels</oasis:entry>  
         <oasis:entry colname="col4">by coarser</oasis:entry>  
         <oasis:entry colname="col5">and boulder</oasis:entry>  
         <oasis:entry colname="col6">silt and clay</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4">sand and gravel</oasis:entry>  
         <oasis:entry colname="col5">deposits with</oasis:entry>  
         <oasis:entry colname="col6"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">intermixed</oasis:entry>  
         <oasis:entry colname="col6"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">layers of clay</oasis:entry>  
         <oasis:entry colname="col6"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">and silt overlying</oasis:entry>  
         <oasis:entry colname="col6"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">consolidated shale</oasis:entry>  
         <oasis:entry colname="col6"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">and limestone</oasis:entry>  
         <oasis:entry colname="col6"/>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p>Extensive research in Germany has shown that these compounds may be removed
to varying degrees, mainly depending on the properties of each compound
(Schmidt et al., 2003). As stated by
Schmidt et al. (2004), the biodegradation of organic
micro-pollutants is a function of the available organic carbon for energy
production. The process of energy production is primarily based on redox
reactions. The extent of biodegradation of an organic micro-pollutant is
dependent on residence time and favorable redox conditions. Therefore,
the elimination rates of certain micro-pollutants vary depending on local
geological and hydrochemical conditions and organic loads of surface
waters and infiltration zones (Schmidt et al., 2004).</p>
</sec>
<sec id="Ch1.S2.SS2">
  <title>Turbidity removal at RBF sites with highly turbid surface waters</title>
      <p>Turbidity removal has been proven to be highly efficient using RBF
(Dash
et al., 2008, 2010; Ray et al., 2008; Saini et al., 2013; Schubert, 2001;
Thakur and Ojha, 2010; Wang, 2003; Wang et al., 1996, 2001; Weiss et al.,
2005). Thakur and Ojha (2010) studied the
variation in turbidity during the extraction of subsurface water for the
supply of drinking water to Haridwar. According to these authors, the river
channel (from the Ganges River in Uttarakhand, India) reached turbidity values of up
to 2500 NTU, and turbidity removals between 99 and 99.9 % were obtained during
RBF. In Table 1, more turbidity removal values are presented from RBF sites
with highly turbid surface waters.</p>
      <p>The RBF system configuration (i.e., vertical or horizontal) does not govern the
suspended solid removal efficiency, as observed in Table 1, since it is not
a function of the travel time or the contact time. The texture of the streambed,
however, influences the media clogging (Hubbs et
al., 2007; Stuyfzand et al., 2006), where external clogging (cake layer
formation) enhances the removal capacity of fine sediments contained in the
water (Veličković, 2005). The removal efficiency of
suspended solids is concentration dependent
(Fallah et al., 2012; Thakur and Ojha,
2010); the higher the suspended solid concentration, the faster the cake
formation, and therefore the higher the turbidity removal capacity. Although
no studies have quantified the role of concentration in entrapment, the
critical particle concentration at which the porous media become clogged has been
determined to be dependent on the ratio of void size to particle size
(Sen and Khilar, 2006). As reported by
Sen and Khilar (2006), the critical
particle concentration increased from 0.35 to 9 % when the ratio of
bead size to particle size was increased from 12 to 40. Therefore, the
removal efficiency of suspended solids is a function of both the filtering
media characteristics (streambed and particle sizes in the aquifer) and the
water quality in terms of suspended particle size and concentration.</p>
</sec>
<sec id="Ch1.S2.SS3">
  <title>Pathogen removal with RBF</title>
      <p>Schijven et al. (2003) showed the efficiency of RBF for
microbial contaminant removal, which depends on flow path length and
residence times; the longer the flow path and the residence time, the higher
the removal. Bacterial removal larger than 2.5 log has been reported in RBF
systems with most of the removal occurring in the first meter of filtration
(Wang, 2003). Cady et al. (2013) studied an RBF system in the Kali
River and achieved removals of 2.7 log for total coliforms and 3.4 log for <italic>E. coli</italic>
(1 log for <italic>E. coli</italic> per 26 m). However, Weiss et al. (2015) found that the total
coliform reduction at two sites was 5.5 and 6.1 on average.</p>
      <p>Virus removal up to 5 log was reported by
Sprenger et al. (2014)
after only 3.8 m of RBF passage (approximately 8 days of residence time),
demonstrating that RBF is a suitable technology for rivers in emerging
countries with regards to virus removal.
Derx et al. (2013) found that
flooding events significantly alter the removal efficiency of viruses in RBF
systems by increasing the advection and dispersion of the viruses through
the aquifer system. The virus concentration in the abstraction wells was
found to increase up to 8 times due to the decrease in travel times.</p>
      <p>Weiss et al. (2005)
reported parasite (<italic>Cryptosporidium</italic> and <italic>Giardia</italic>) removal at three RBF facilities, where no
parasites were detected in the well waters.
Metge et al. (2010) studied the parasite (<italic>Cryptosporidium parvum</italic>) removal efficiency in an RBF system
comprised of well-graded, metal-oxide-rich content sediments and found that
the main immobilization mechanism was sorption to the metal oxide contents
(iron and aluminum).</p>
</sec>
<sec id="Ch1.S2.SS4">
  <title>Nutrient removal with RBF</title>
      <p>Doussan et al. (1997) studied the behavior
of nitrogen as nitrate, nitrite and ammonium in an RBF system fed by the
Seine River. They found a complete removal of nitrate and nitrite, while the
ammonium concentrations at the RBF site increased in comparison to the
concentration in the river water.
Regnery et al. (2015) also found a
significant decrease in nitrate concentrations through denitrification. The
presence of reducing conditions is commonly found during RBF passage due to
the long paths and residence times of the water transported from the river
to the RBF abstraction wells. Ammonium concentrations are usually low in
surface waters due to the nitrification processes occurring in rivers.
However, even low ammonium concentrations can cause an extensive oxygen
reduction during infiltration (Doussan et
al., 1997). By contrast, Wu et al. (2007) reported a
decrease in ammonium concentrations and an increase in nitrate and nitrite
concentrations in an unsaturated RBF passage, associated with oxic
conditions leading to nitrification processes. They reported removals of
nitrogen over 95 % through nitrification and denitrification under saturated
conditions during the monitoring period. The ammonium concentrations in the
river water corresponded to a highly polluted river (16.42 mg L<inline-formula><mml:math id="M14" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>; Wu et al., 2007).</p>
      <p>Phosphorus is generally removed by sorption and precipitation in the form of
calcium, iron or aluminum or iron phosphate
(Regnery et al., 2015; Schmidt
et al., 2003). Phosphorus removal is influenced by the sedimentary structure
of the subsoil (Hendricks and White, 2000). Its sorption is
linked to the exchange between the river water and the soil matrix
(Hülshoff et al., 2009;
Smith, 2005). Leader
et al. (2008) assessed the sorption dynamics for different materials and
found sorption ranging from 66 to 97 mg-P kg<inline-formula><mml:math id="M15" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for clean sand and about
515 mg-P kg<inline-formula><mml:math id="M16" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for iron-coated sand. As stated by
Vohla et al. (2007), the amount of
phosphate that can be removed during subsurface passage is limited to the
number of sorption sites, leading to a sorption capacity decrease over time
and changes in the physicochemical and oxidation conditions.
Regnery et al. (2015) found a decrease
in the phosphate removal efficiency in an RBF system from 80 % during
start-up to 40 % after 6 years.</p>
</sec>
<sec id="Ch1.S2.SS5">
  <title>Heavy metal removal with RBF</title>
      <p>RBF has been shown to be a suitable technology to remove certain heavy metals
(Bordas and Bourg, 2001; Bourg
et al., 1989; Bourg and Bertin, 1993; Stuyfzand, 1998), although its ability
is site and substance specific. As pointed out by Sontheimer (1980), Schmidt et al. (2003) and
Stuyfzand et al. (2006), some RBF systems are able to
remove heavy metals, such as chromium, and metalloids, like arsenic, by
approximately 90 %. This is in accordance with experiences in the use
of similar technologies, like sand filtration, also resulting in the removal
of heavy metals (Awan et al.,
2003; Baig et al., 2003; Schmidt and Stadtwerke, 1977).
Schmidt et al. (2003) also found lead and cadmium
removals of up to 75 % at an RBF site located in Germany with water
abstracted
from the Rhine River. However, Stuyfzand et al. (2006) found that lead and cadmium concentrations in the abstraction wells
increased by over 300 and 30 %, respectively, within a 450-day travel time.
Bourg et al. (1989) also found that cadmium and zinc
were remobilized from sediments, although
Bourg and Bertin (1993) still reported zinc
removal by riverbank sediments.</p><?xmltex \hack{\newpage}?>
</sec>
<sec id="Ch1.S2.SS6">
  <title>Micro-pollutant removal with RBF</title>
      <p>Hamann et al. (2016) analyzed
the fate of 29 micro-pollutant compounds in an RBF system considering a
travel time of up to 3.6 years and found the complete removal of 14 compounds
(2-naphthalene sulfonate, 2,6-NDS, amidotrizoic acid, AMPA, aniline,
bezafibrate, diclofenac, ibuprofen, iohexol, iomeprol, iopromide,
ioxitalamic acid, metoprolol and sulfamethoxazole) due to retardation and
degradation processes as supported by numerical modeling. In addition,
some compounds were partially removed (triglyme, iopamidol, diglyme,
1,3,5-naphthalene trisulfonate and 1,3,6-naphthalene trisulfonate) with
removal efficiencies ranging from approximately 60 to 90 %, based on the
highest concentrations measured in both the Lek River and the observation well
(906 m from the river; 3.65 years of travel time). Only 10 compounds were fully
persistent during the subsurface passage in the RBF system (1,4-dioxane,
1,5-naphthalene disulfonate (1,5-NDS), 2-amino-1,5-NDS, 3-amino-1,5-NDS,
AOX, carbamazepine, EDTA, MTBE, toluene and triphenylphosphine oxide). The
authors do not differentiate between biodegradation and sorption where
adsorption, ion-pair formation and the complexation of pollutants to the soil
may lead to soil pollution (Bradl, 2004).</p>
      <p>Bertelkamp et al. (2014)
assessed the sorption and biodegradation of 14 organic micro-pollutants
(acetaminophen, ibuprofen, ketoprofen, gemfibrozil, trimethoprim, caffeine,
propranolol, metoprolol, atrazine, carbamazepine, phenytoin,
sulfamethoxazole, hydrochlorothiazide and lincomycin) at laboratory scale
and found that most of them (the first eight compounds listed above) were
completely biodegraded. However, compounds such as atrazine and
sulfamethoxazole were not removed in a 6-month period.
Schmidt et al. (2003) found that sulfamethoxazole was
primarily removed (20 % removal efficiency) under anaerobic conditions
(anaerobic aquifer), while only slightly reduced in the RBF system under
aerobic conditions. Drewes et al. (2003)
examined the fate of selected pharmaceuticals and personal care products
during groundwater recharge; the stimulants caffeine,
diclofenac, ibuprofen, ketoprofen, naproxen, fenoproxen and gemfibrozil
were efficiently removed. However, the antiepileptics carbamazepine and
primidone were not removed at all. Organic iodine was only partially
removed. The formation of metabolites may be expected during organic
micro-pollutant biodegradation; however, this has not been reported.</p>
      <p>Schmidt et al. (2004) studied the fate of anthropogenic
organic micro-pollutants comprised of aminopolycarboxylates (EDTA, NTA and DTPA),
aromatic sulfonates (2-aminonaphthalene-1,5-NDS, 1,3,6-naphthalene
trisulfonate, 1,5-NDS, 1- naphthalene sulfonate and 2-naphthalene
sulfonate), pharmaceutical compounds (diclofenac, carbamazepine, bezafibrate
and sulfamethoxazole), iodinated x-ray contrast media (iomeprol,
amidotrizoic acid and iopamidol) and MTBE. Schmidt et al. (2004) found that sulfamethoxazole was primarily removed (20 % removal
efficiency) under anaerobic conditions (anaerobic aquifer), while only
slightly reduced in the RBF system under aerobic conditions. The reduction
in EDTA concentrations under aerobic conditions was higher than that achieved
under denitrifying and anaerobic redox conditions. In addition, the EDTA
concentrations in the filtrated water were higher than those measured in the
surface water; the conclusion is that the DTPA was partially biodegraded, leading to
the formation of EDTA as a metabolite (Schmidt et al.,
2004).</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <title>Clogging and self-cleansing in RBF</title>
<sec id="Ch1.S3.SS1">
  <title>Hydraulic conductivity and clogging of the aquifer</title>
      <p>RBF systems worldwide have shown a decline in the long-term yield
(Caldwell,
2006; Dash et al., 2010; Hubbs, 2006a; Hubbs et al., 2007; Mucha et al.,
2006; Schmidt et al., 2003; Schubert, 2006a; Stuyfzand et al., 2006). The
production yield of RBF depends on many factors, including the hydraulic
conductivity and the degree of contact between the river and the phreatic
aquifer (Caldwell, 2006). Temperature affects the production
yield seasonally due to changes in water viscosity
(Caldwell, 2006; Hubbs, 2006a); however, this parameter is
not a concern in tropical countries like Colombia where the temperature in
surface water sources remains largely constant throughout the entire year
(Lewis, 2008).</p>
      <p>Commonly, hydraulic conductivity varies spatially and can be temporally
dependent on clogging and interface renewal through scouring. The clogging
layer leads to a reduction in the hydraulic conductivity of the streambed and
then affects the hydraulic connectivity between the river and the aquifer.
This alters the interaction between the surface water and the groundwater and therefore may
influence the abstraction capacity yield
(Brunke, 1999; Packman and
MacKay, 2003). Nevertheless, the clogging might be favorable for quality
improvement due to longer travel times and greater particulate removal, as
discussed previously.</p>
      <p>Clogging has been identified as the major contributor to the long-term decay
of RBF yield (Hubbs et al., 2007), but there is a lack of
understanding of the exact factors that affect clogging
(Caldwell, 2006; Hubbs et al., 2007;
Schubert, 2006a; Stuyfzand et al., 2006). Hubbs et al. (2007) reported a decrease in the specific capacity of the wells of up to
67 % of the initial level in the first 4-year period of operation. Most of
the reduction took place within the first year due to riverbed clogging in
the vicinity of the well. Clogging is time dependent and is a function of the
bed material
(Goldschneider et al.,
2007; Rehg et al., 2005), the shear forces
(Hubbs, 2006b; Schubert, 2006b) scouring out the
deposited material on the riverbed (Hubbs, 2006a; Mucha et
al., 2006), which are seasonally variable, and the content and composition of the suspended load
and the
transported bed load material (Bouwer,
2002; Holländer et al., 2005).</p>
      <p>Generally, the suspended sediment load carried by the rivers during the rainy
season is higher than that found during the dry season
(Dunlop et al., 2008;
Göransson et al., 2013); however, in regulated river systems, seasonal
variations in load do not always follow such a trend
(Göransson et al., 2013). Shear forces are
also seasonally variable, since these forces are a function of the water
level (Hubbs, 2006b). As stated by
Regnery et al. (2015), high discharge
rates create higher flow velocities and shear stress, which usually results
in higher infiltration rates, indicating a lower degree of clogging. By
contrast, low discharge rates commonly lead to an increase in pore clogging
and then to a lower production yield for an RBF system.</p>
      <p>Clogging can be caused by physical, chemical and biological processes,
although physical clogging has been found to be the dominant mechanism over
the other forms of clogging
(Pavelic et al., 2011;
Rinck-Pfeiffer et al., 2000). As water flows from the river and through the
aquifer to the RBF system, the larger silt particles plug the pore channels
to the aquifer in the riverbed and form a less permeable layer together with
smaller particles (Grischek and Ray, 2009;
Veličković, 2005). Tropical river conditions (temperature and
nutrient loads) may be favorable for biological growth onto the riverbed,
which might lead to biological clogging
(Kim et al., 2010;
Platzer and Mauch, 1997; Vandevivere et al., 1995).
Rinck-Pfeiffer et al. (2000) reported biological clogging
by biomasses and bacterially produced polysaccharides in a simulated aquifer
storage and recovery well system; this was related to the high presence of
nutrients. Hoffmann and Gunkel (2011)
reported severe clogging mainly induced by biological processes in Lake
Tegel reaching a depth of at least 10 cm.</p>
      <p>As pointed out by Hubbs et al. (2007), medium-coarse sand
to fine gravel in the riverbed is desirable, so that little fine sand
and silt can penetrate the larger voids in the aquifer; a
permanent reduction in the hydraulic conductivity of the aquifer may therefore be
avoided. However, Sakthivadivel and Einstein (1970) stated
that if the ratio between the bed particle and the suspended particle is
larger than 20, clogging of the bed occurs. Also, experiences from the
Netherlands have suggested that riverbeds consisting primarily of gravel (up
to 25 cm in size) are at a greater risk of clogging than those consisting
primarily of finer-grade materials (Stuyfzand et al.,
2006). This is due to the fact that the finer particles will be able to
penetrate a greater distance into the gravel riverbed before clogging
(Veličković, 2005). Consequently, there is a
reduced chance of resuspension or scouring of these particles; the gravel
bed acts as a protective shield from flow shear forces, and infiltration
rates become permanently impaired
(Goldschneider et al., 2007). In sandy and
silty riverbeds, the clogging particles cannot penetrate as deeply, and a
cake layer will be formed on the riverbed surface
(Brunke, 1999; Veličković,
2005). In these instances, flood waves will more easily be able to resuspend
and remove the clogging particles, thereby regenerating bed infiltration
rates to some degree.
Levy et al. (2011)
estimated a recovery of the hydraulic conductivity by a factor of 1.5 (from
31 to 47 % compared to the hydraulic conductivity of the media before
clogging).</p>
      <p>Aquifers hydraulically connected to surface waters are susceptible to the
long-term accumulation of micro-sized (colloidal) particles
(Baveye et al., 1998; Hiscock and Grischek,
2002; Vandevivere et al., 1995), which causes a reduction in the hydraulic
conductivity, leading to a reduction in production yield capacity.
Hoffmann and Gunkel (2011) reported a
decrease in the hydraulic conductivity in a bank filtration system of about
2 orders of magnitude during the winter period. As stated by
Hoffmann and Gunkel (2011), the water
temperature decrease only amounted to a change in hydraulic conductivity
from 4.8 <inline-formula><mml:math id="M17" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M18" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> to 3.1 <inline-formula><mml:math id="M19" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M20" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> m s<inline-formula><mml:math id="M21" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. Thus, clogging by micro-sized
particles (e.g., particulate organic matter) in combination with atmospheric
air intrusion was considered to be the main factor in reducing the hydraulic
conductivity. The clogging of the aquifer also depends on the concentration
and type of micro-sized particles (Zamani
and Maini, 2009). As stated by Okubo and Matsumoto (1983), the concentration should be below 2 mg L<inline-formula><mml:math id="M22" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> to sustain a high
infiltration capacity during long inundation periods. In addition,
Jacobsen et al. (1997) reported
that particles &lt; 10 <inline-formula><mml:math id="M23" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m are absorbed more strongly at the
macropore wall due to their relatively large surface charge, while
particles &gt; 10 <inline-formula><mml:math id="M24" display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m are more exposed to hydraulic force.</p>
</sec>
<sec id="Ch1.S3.SS2">
  <title>Interface renewal by scouring</title>
      <p>The deposition of sediments carried by river water on the riverbed surface
must be balanced by scouring in order for an RBF system to be
sustainable. Naturally occurring flow forces may induce sufficient scouring
of the riverbed, thereby self-regulating the thickness of the formed cake
layer, scouring the bed and restoring its hydraulic conductivity. Scouring
is the result of shear stress forces exerted on the riverbed. The extent of
scouring is determined by the magnitude of the shear stress and the
properties of the riverbed and armor layer deposited onto the riverbed. The
shear stress is mainly a function of the fluid velocity and water level at the
streambed (Hubbs et al., 2007; Stuyfzand et al.,
2006). Shear stress values have been reported to range between 1 and 100 N m<inline-formula><mml:math id="M25" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> as typical for river streambeds, considering a value of
20 N m<inline-formula><mml:math id="M26" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> as reasonable for the design of an RBF (Hubbs, 2006b).
Schubert (2002) estimated an approximate average shear
stress of 10 N m<inline-formula><mml:math id="M27" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in the Lower Rhine River region at the Flehe
waterworks. Hubbs (2006b) reported a minimum shear stress
(during low-flow conditions) of 0.2 N m<inline-formula><mml:math id="M28" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> and a maximum shear stress of
9.16 N m<inline-formula><mml:math id="M29" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (during high-flow conditions) in the Ohio River at
Louisville, Kentucky. While flood events may stimulate riverbed renewal by
streambed scouring as a result of shear forces, low-flow periods may
promote the sedimentation of suspended solids at the riverbed
(Levy et
al., 2011; Stuyfzand et al., 2006). However, Schubert (2002) stated that flood events might also induce riverbed clogging due to
the higher concentration of suspended solids and a higher gradient between
the river level and the water table of the aquifer.</p>
      <p>The scouring or self-cleansing capacity of RBF systems is commonly assessed in
terms of critical shear stress, which depends on riverbed particle
characteristics (considering its critical shear stress) and the shear stress
exerted by the river water velocity. The viscosity and density of the fluid
contribute to shear stress forces (Hubbs et al., 2007), but
these properties are expected to be constant in time for tropical rivers
(Lewis, 2008). The velocity of the fluid at the
streambed is a function of the stream surface slope, water level and
resistance to the flow transmitted by the streambed. These parameters vary in
time and place, determining the sediment transport capacity on the surface
of the streambed (Hubbs et al., 2007).</p>
      <p>Erosion and deposition behave dissimilarly for cohesive and non-cohesive
sediments (Winterwerp and van Kesteren, 2004).
Ahmad et al. (2011) experimentally studied the
critical shear stress using sand and different mud mixtures. They found an
increase in the critical shear stress by a factor of 1.5 for a mixture with
a mud fraction of 50 % in comparison to only sand. For non-cohesive
sediments, when the bed shear stress is greater than the critical shear stress,
erosion and deposition occur simultaneously (Krishnappan,
2007). By contrast, for cohesive sediments, erosion and deposition do not
act simultaneously for all shear stress conditions due to the electrochemical
and biological processes binding the cohesive particles to the riverbed.
Armor layers made from the deposition of cohesive materials carried by the
rivers will increase their resistance to erosive processes, resulting in
higher shear stresses to move the sediments deposited on the riverbed. In
addition, the shear stress for the deposition of cohesive sediments is different
from the shear stress for erosion (Krishnappan, 2007). As
stated by Berlamont et al. (1993), the critical shear
stress for deposition is usually in the range of 0.05–0.2 N m<inline-formula><mml:math id="M30" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>,
while
for erosion it is in the range of 0.1–2 N m<inline-formula><mml:math id="M31" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. Moreover, cohesive sediments
consolidate over time when deposited on a bed, altering the critical shear
stress for erosion through compaction (Krishnappan and Engel,
1994), while their bulk densities tend to increase as a function of depth
and time (Lick, 2008). Jepsen et al. (1997)
studied the changes in bulk density as a result of depth and consolidation
time in the Detroit River, the Fox River and the Santa Barbara slough.
Although different bulk densities were obtained among the locations, the
density variation trends were similar. Thus, there was an increase in the bulk density
by depths of up to 0.2 % cm<inline-formula><mml:math id="M32" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in the river sediments and 0.7 % cm<inline-formula><mml:math id="M33" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in the
slough sediments. Regarding the consolidation time, it increases up to 0.1 % days<inline-formula><mml:math id="M34" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>
in the river sediments and up to 0.3 % days<inline-formula><mml:math id="M35" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in the slough sediments.
Therefore, bed age or consolidation time might play an important role in
critical shear stress values and erosion rates for deposited cohesive
sediments
(Droppo
and Amos, 2001; Jepsen et al., 1997; Krishnappan and Engel, 1994; Stone et
al., 2008; Valentine et al., 2014).</p>
</sec>
</sec>
<sec id="Ch1.S4" sec-type="conclusions">
  <title>Discussion about the applicability of RBF in Colombia</title>
      <p>It may be concluded that RBF is a technology appropriate for use in the highly
turbid and contaminated surface rivers in Colombia
(Gutiérrez et al., 2016) due to its capacity to remove a
high variety of pollutants linked to the influence of the highly suspended
sediment loads carried by the rivers. As a consequence of the suspended
sediments, cake formation on the riverbed and clogging of the aquifer may
occur (Caldwell, 2006), contributing to the removal of most
dissolved and suspended contaminants (Ray, 2002a). In addition,
good water quality can be obtained at the abstraction wells, requiring only
a few additional treatment steps for the production of drinking water
(Singh
et al., 2010; Sprenger et al., 2014; Thakur and Ojha, 2010).</p>
<sec id="Ch1.S4.SS1">
  <title>Comparative assessment of water treatment technologies</title>
      <p>In Colombia, conventional surface water treatment plants
(involving coagulation, flocculation, sedimentation, filtration and chlorination) are currently used
to supply drinking water. As stated by Gutiérrez et al. (2016), in Colombian WTPs the operation, maintenance and sludge
disposal are the main processes leading to costly water production. The
costs are linked to chemical usage, sludge production and its treatment. The
following
brief comparison of robust drinking water technologies in the removal of
turbidity, pathogens and the chemical contaminants discussed in this
review is based on the analysis conducted by
Hubbs et al. (2003) and Ray and Jain (2011). Slow sand filtration, with pretreatment, is mainly suitable for
small- to medium-sized communities, whereas RBF and conventional WTP can be
suitable for small to very large communities (Ray and Jain,
2011). RBF is suitable for highly contaminated rivers, and is able to match
conventional treatments, including advanced technologies such as ozone,
ultraviolet light and granular-activated carbon, for pesticide removal.
Although using a conventional train with the steps coagulation, sedimentation, filtration, activated carbon filtration and disinfection
(O<inline-formula><mml:math id="M36" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>, UV, H<inline-formula><mml:math id="M37" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O<inline-formula><mml:math id="M38" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>, Cl<inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and an alternative train with the steps RBF, aeration, filtration, activated carbon filtration and disinfection
(O<inline-formula><mml:math id="M40" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>, UV, H<inline-formula><mml:math id="M41" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O<inline-formula><mml:math id="M42" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>, Cl<inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> may produce similar water qualities,
there are differences in the production costs. The use of RBF leads to
savings in chemical dosing, sludge handling and filter backwashing. As
reported by Sharma and Amy (2009), the conversion from a
conventional WTP to a process including an RBF system may reduce the
operational costs by up to 50 %. Moreover, the sedimentation step may be
skipped, and the advanced removal of pathogens is no longer needed. As reported
by Dusseldorp (2013), after anaerobic riverbank filtrate is
extracted in a WTP train in the Netherlands, water is pretreated with
reverse osmosis prior to the conventional treatment steps of sand filtration,
granular-activated carbon and UV disinfection in order to be used in
combination with membrane filtration and avoid ultrafiltration and
biofouling. RBF has the advantage over the other assessed technologies of
dampening shock loads and peaks, which is a need in rivers with extremely
variable water qualities, such as the Colombian rivers (e.g., the Cauca River;
Fig. 2).</p>
</sec>
<sec id="Ch1.S4.SS2">
  <title>Potential challenges in the application of RBF in conventional surface water
treatment plants in Colombia</title>
      <p>RBF as an alternative pretreatment step may provide an important reduction
in chemical consumption, considerably simplifying the operation of the
existing treatment processes. It is expected that employing RBF in
communities where the conditions are appropriate for its implementation
(e.g., located in an alluvial formation and close to a river) will lead to
considerable improvements in source water quality. Mainly, improvements are expected due
to the removal of turbidity, pathogens and to a lesser extent
inorganics, organic matter and micro-pollutants. Furthermore,
in Colombia, shock loads of pollutants commonly lead to shutdowns of water
treatment plants until the peak has passed
(Gutiérrez et al., 2016; Pérez-Vidal
et al., 2012). RBF has the potential to mitigate shock loads
(Schmidt et al., 2003), thus leading to the prevention of
shutdowns of water treatment plants.</p>
      <p>During the application of RBF in conventional surface WTPs in Colombia, many
of the treatment processes currently employed could be varied or even
removed completely, leading to simpler plant operation and control. In the
specific case of the Puerto Mallarino WTP in Cali, Colombia, RBF would
replace all current pretreatment process steps occurring in the grit
chamber, the rapid mix chamber and the flocculation and settling clarifiers
(Gutiérrez et al., 2016). Chemical doses could be reduced
in all remaining processes, but an additional requirement for aeration
directly after well extraction may be needed. However, this would only be
necessary in the instance that the RBF filtrate had become anaerobic during
soil passage. Because of the process changes, a stable inflow quality
(turbidity, temperature, pH and electrical conductivity) means that the
plant will operate under more stable conditions, thereby increasing plant
efficiency and effluent quality. RBF well operation and control is much
simpler than the existing treatment steps, which currently require continual
adjustment to ensure smooth plant operation according to any changes in raw
water quality. Additionally, a complete reduction in the sludge produced by
the grit chambers and clarifiers would be achieved.</p>
      <p>RBF thus typically results in fewer environmental impacts than conventional
surface water treatment. The environmental benefits can mainly be attributed
to its considerable reductions in chemical usage and sludge production.
Likewise, the elimination of surface water intake structures may have a
positive effect on the surrounding aquatic environment. However, the high
sediment loads contained in many Colombian rivers may lead to some negative
environmental impacts with the use of RBF, mainly associated with changes in
vital aquatic habitats caused by riverbed clogging (Kendy and
Bredehoeft, 2007).</p>
      <p>The suspended sediments responsible for the clogging processes may, on the
one hand, be favorable for the improvement of the water quality, mainly due to
the strengthening of cake filtration and deep bed filtration processes. On
the other hand, the formed cake layer must be balanced by scouring in order
for an RBF system to be sustainable. Therefore, clogging and self-cleansing
issues must be studied in greater depth to assess the use of RBF technology
in highly turbid waters; they may affect the abstraction capacity
yield as well as the development of different redox zones for efficient
contaminant removal.</p>
      <p>Finally, in the design of an RBF system, a balance between the water quality
and the production capacity must be sought. Greater removal efficiencies may
be achieved with increased travel distances (residence time), yet there is
an inevitable trade-off between the ability to supply large flows and the
decreased water quality in the abstraction wells. The longer the travel
distance, the higher the fraction of groundwater extracted from storage in the
aquifer; therefore, the lower the extraction capacity of the system
(de Vet et al., 2010). For an RBF system to
be sustainable, the infiltration rate must remain high enough throughout the
river–aquifer interface in order to provide the water quantity needed, and
the residence time of the contaminants must be sufficient to ensure adequate
water quality. Nonetheless, even with shorter residence times, the
abstracted water will have better characteristics than the raw water, making
further treatment steps such as coagulation, flocculation and sedimentation
redundant. Therefore, RBF may be considered a feasible option to address
water quality changes at a larger scale.</p>
</sec>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability">

      <p>No data sets were used in this article.</p>
  </notes><notes notes-type="competinginterests">

      <p>The authors declare that they have no conflict of interest.</p>
  </notes><ack><title>Acknowledgements</title><p>The authors would like to acknowledge the support of Colciencias for the scholarship of Juan Pablo Gutiérrez Marín.
<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
Edited by: B. Mamba<?xmltex \hack{\newline}?>
Reviewed by: three anonymous referees</p></ack><ref-list>
    <title>References</title>

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    </app></app-group></back>
    <!--<article-title-html>Riverbank filtration for the treatment of highly turbid Colombian rivers</article-title-html>
<abstract-html><p class="p">The poor quality of many Colombian surface waters forces us
to
seek alternative, sustainable treatment solutions with the ability to
manage peak pollution events and to guarantee the uninterrupted provision of
safe drinking water to the population. This review assesses the potential of
using riverbank filtration (RBF) for the highly turbid and contaminated
waters in Colombia, emphasizing water quality improvement and the influence
of clogging by suspended solids. The suspended sediments may be favorable for
the improvement of the water quality, but they may also reduce the production yield
capacity. The cake layer must be balanced by scouring in order for an RBF
system to be sustainable. The infiltration rate must remain high enough
throughout the river–aquifer interface to provide the water quantity
needed, and the residence time of the contaminants must be sufficient to ensure
adequate water quality. In general, RBF seems to be a technology
appropriate for use in highly turbid and contaminated surface rivers in
Colombia, where improvements are expected due to the removal of turbidity, pathogens
and to a lesser extent inorganics, organic matter and micro-pollutants. RBF has the potential to mitigate shock loads, thus leading to the
prevention of shutdowns of surface water treatment plants. In addition, RBF,
as an alternative pretreatment step, may provide an important reduction in
chemical consumption, considerably simplifying the operation of the
existing treatment processes. However, clogging and self-cleansing issues
must be studied deeper in the context of these highly turbid waters to
evaluate the potential loss of abstraction capacity yield as well as the
development of different redox zones for efficient contaminant removal.</p></abstract-html>
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